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Max Planck discovers the law of black body emission19.10.1900
In 1894 Planck turned his attention to the problem of black-body radiation. He had been commissioned by electric companies to create maximum light from lightbulbs with minimum energy. The problem had been stated by Kirchhoff in 1859: "how does the intensity of the electromagnetic radiation emitted by a black body (a perfect absorber, also known as a cavity radiator) depend on the frequency of the radiation (i.e., the color of the light) and the temperature of the body?". The question had been explored experimentally, but no theoretical treatment agreed with experimental values. Wilhelm Wien proposed Wien's law, which correctly predicted the behaviour at high frequencies, but failed at low frequencies. The Rayleigh–Jeans law, another approach to the problem, created what was later known as the "ultraviolet catastrophe", but contrary to many textbooks this was not a motivation for Planck.
Planck's first proposed solution to the problem in 1899 followed from what Planck called the "principle of elementary disorder", which allowed him to derive Wien's law from a number of assumptions about the entropy of an ideal oscillator, creating what was referred-to as the Wien–Planck law. Soon it was found that experimental evidence did not confirm the new law at all, to Planck's frustration. Planck revised his approach, deriving the first version of the famous Planck black-body radiation law, which described the experimentally observed black-body spectrum well. It was first proposed in a meeting of the DPG on October 19, 1900 and published in 1901. This first derivation did not include energy quantisation, and did not use statistical mechanics, to which he held an aversion. In November 1900, Planck revised this first approach, relying on Boltzmann's statistical interpretation of the second law of thermodynamics as a way of gaining a more fundamental understanding of the principles behind his radiation law. As Planck was deeply suspicious of the philosophical and physical implications of such an interpretation of Boltzmann's approach, his recourse to them was, as he later put it, "an act of despair ... I was ready to sacrifice any of my previous convictions about physics."
